There are a bunch of things you can do on the front-end (html/javascript) to make it faster:
Enabling browser caching of your static content should be high up on your list. It will make navigating the site and repeat visits quite a bit faster. If you’re using W3 Total Cache you just need to turn on browser caching of css and javascript (and make sure to change the cache control headers to use public and not re-validate).
It looks like you are still serving some CSS from your main domain (and your main domain is set to not allow for keep-alive connections).
If you can, move all of your javascript except for the ads to the end of the HTML. I don’t see anything in the UI that needs to load jquery and the rest of the javascript before the HTML is loaded. It looks like you are loading a BUNCH of JQueryUI modules at the end of the html - are those all actually used on the site? The UI looks very static so I’m surprised to see so much javascript getting loaded.
The Digg Digg plugin looks like it is using blocking scripts for all of the social buttons. You should see if there is an update or go back to the author to ask them to use the async versions instead.